Table 5 Summary statistics of ion ratio monitoring
Reference Measurement Procedure | |||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
GISSTTVTGR Qualifier 2 | GISSTTVTGR Qualifier 1 | GISSTTVTGR-SIL Qualifier 2 | GISSTTVTGR-SIL Qualifier 1 | LFLEPTQADIALLK Qualifier 1 | LFLEPTQADIALLK Qualifier 2 | LFLEPTQADIALLK-SIL Qualifier 1 | LFLEPTQADIALLK-SIL Qualifier 2 | TPENYPNAGLTR Qualifier 1 | TPENYPNAGLTR Qualifier 2 | TPENYPNAGLTR-SIL Qualifier 1 | TPENYPNAGLTR-SIL Qualifier 2 | ||
Batch 1 | Average ion ratio | 39 | 59 | 34 | 57 | 128 | 14 | 133 | 13 | 34 | 19 | 35 | 19 |
CV (%) | 8.0 | 7.7 | 10.4 | 9.8 | 9.0 | 7.3 | 8.1 | 12.8 | 38.1 | 27.2 | 25.3 | 22.4 | |
Batch 2 | Average ion ratio | 38 | 59 | 34 | 57 | 129 | 14 | 133 | 13 | 32 | 19 | 33 | 19 |
CV (%) | 8.5 | 8.3 | 10.8 | 9.3 | 10.5 | 7.8 | 8.3 | 12.6 | 34.0 | 24.4 | 24.7 | 21.9 | |
Designated Comparison Method | |||||||||
|---|---|---|---|---|---|---|---|---|---|
GISSTVTGR Qualifier 1 | GISSTVTGR Qualifier 2 | GISSTTVTGR-SIL Qualifier 1 | GISSTTVTGR-SIL Qualifier 2 | LFLEPQADIALLK Qualifier 1 | LFLEPTQADIALLK Qualifier 2 | LFLEPTQADIALLK-SIL Qualifier 1 | LFLEPTQADIALLK-SIL Qualifier 2 | ||
Batch 1 | Average ion ratio | 31 | 50 | 30 | 59 | 15 | 27 | 14 | 59 |
CV (%) | 9.2 | 14.2 | 16.7 | 5.1 | 11.8 | 6.9 | 5.3 | 8.7 | |
Batch 2 | Average ion ratio | 33 | 56 | 33 | 61 | 15 | 29 | 15 | 45 |
CV (%) | 11.9 | 13.3 | 13.3 | 7.9 | 10.6 | 10.2 | 8.7 | 24.6 | |
Batch 3 | Average ion ratio | 33 | 53 | 31 | 59 | 15 | 30 | 14 | 50 |
CV (%) | 17.8 | 18.5 | 12.0 | 8.9 | 26.0 | 18.6 | 8.5 | 16.6 | |
Batch 4 | Average ion ratio | 34 | 54 | 31 | 60 | 15 | 30 | 14 | 51 |
CV (%) | 21.2 | 19.9 | 11.7 | 9.7 | 25.1 | 18.0 | 9.0 | 15.9 | |
Batch 5 | Average ion ratio | 35 | 53 | 33 | 58 | 15 | 29 | 14 | 48 |
CV (%) | 22.1 | 20.7 | 17.6 | 11.7 | 22.6 | 20.9 | 10.8 | 21.1 | |
Batch 6 | Average ion ratio | 36 | 52 | 33 | 57 | 15 | 29 | 14 | 47 |
CV (%) | 22.8 | 19.6 | 16.8 | 11.8 | 21.7 | 19.3 | 10.4 | 19.8 | |